Expedient on-resin modification of a peptide C-terminus through a benzotriazole linker† †Electronic supplementary information (ESI) available: Experimental procedure and NMR spectra of synthetic peptides and relative derivatives. See DOI: 10.1039/c7sc03229c

Selective glycoprotein detection through covalent templating and allosteric click-imprinting† †Electronic supplementary information (ESI) available: Synthetic procedures, synthesis of DFC, NMR spectra, surface modification and characterisation in addition to SPR analysis. See DOI: 10.1039/c5sc02031j Click here for additional data file.

Self-assembling α,γ-cyclic peptides that generate cavities with tunable properties† †Electronic supplementary information (ESI) available: Synthetic experimental details, DFT calculation details, additional figures (relevant NMR data) and schemes (synthetic schemes for peptide and amino acid preparation). CCDC 1400134. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc03187g Click here for additional data file. Click here for additional data file.

A thiocyanopalladation/carbocyclization transformation identified through enzymatic screening: stereocontrolled tandem C–SCN and C–C bond formation† †Electronic supplementary information (ESI) available: Enzymatic screening procedures, detailed synthetic procedures and compilations of spectroscopic data, as well as copies of NMR spectra for new compounds. CCDC 1513686 and 1513687. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04083k

3-Mercaptopropionic acid-mediated synthesis of peptide and protein thioesters† †Electronic supplementary information (ESI) available: Experimental procedures for the production of 1, all model peptides and proteins and their reactions with MPA including HPLC, LC-MS and NMR characterisation of selected products. See DOI: 10.1039/b815888f Click here for additional data file.

Peptides and proteins fragment sequence-specifically in the presence of 3-mercaptopropionic acid to afford thioesters which can be used in native chemical ligation reactions.

Catalyst-controlled polycondensation of glycerol with diacyl chlorides: linear polyesters from a trifunctional monomer† †Electronic supplementary information (ESI) available: Synthetic protocols, characterization data, NMR and IR spectral data and GPC chromatograms. See DOI: 10.1039/c7sc01886j Click here for additional data file.

General ............................................................................................................................................ 1 Polymer Synthesis ........................................................................................................................... 2 Isolation of Unfractionated Polymers ....................................................................